Structural correlations in three-dimensional network solids

Covalently interconnected three-dimensional graphene oxide solids.

The creation of three-dimensionally engineered nanoporous architectures via covalently interconnected nanoscale building blocks remains one of the fundamental challenges in nanotechnology. Here we report the synthesis of ordered, stacked macroscopic three-dimensional (3D) solid scaffolds of graphene oxide (GO) fabricated via chemical cross-linking of two-dimensional GO building blocks. The resu...

Three-dimensional magnetic correlations in multiferroic LuFe2O4.

We present single crystal neutron diffraction measurements on multiferroic LuFe(2)O(4). Magnetic reflections are observed below transitions at 240 and 175 K indicating that the magnetic interactions in LuFe(2)O(4) are three-dimensional in character. The magnetic structure is refined as a ferrimagnetic spin configuration below the 240 K transition. Below 175 K a significant broadening of the mag...

Three-dimensional protonic conductivity in porous organic cage solids

Proton conduction is a fundamental process in biology and in devices such as proton exchange membrane fuel cells. To maximize proton conduction, three-dimensional conduction pathways are preferred over one-dimensional pathways, which prevent conduction in two dimensions. Many crystalline porous solids to date show one-dimensional proton conduction. Here we report porous molecular cages with pro...

Three-Dimensional Network Topologies

This paper presents the derivation and performance results of several new three-dimensional topologies. Various transformations can be applied to the conventional six-neighbor mesh in order to construct these topologies, which vary both in number of neighbors (degree) and logical connectivity. Analysis shows that after normalization for constant pin-count, lower-degree topologies yield lower la...

Structural transitions in solids.